In September, a team of astronomers made a startling announcement: They had detected the signature of a gas called phosphine in the atmosphere of Venus, a chemical that, on Earth, is created by life. It turns from a liquid to a gas at -126 degrees F—well below even the coldest place on earth, so once it forms, it evaporates … Inhalation is the major route of phosphine toxicity. Scientists are also holding out hope that no matter what happens with phosphine, this possible discovery has stoked excitement in jumpstarting new missions to Venus. On Earth, phosphine is a flammable, foul, toxic gas produced by bacteria that doesn't require oxygen -- like those in swamps, wetlands, sludge or even animal guts… The team, which includes researchers from the UK, US and Japan, estimates that phosphine exists in Venus’ clouds at a small concentration, only about 20 molecules in every billion. The gas product analyzed by gas chromatography contained phosphine (yield up to 0.6 g/kg phosphate) and methylphosphine (CH3)PH2 (yield up to 0.02 g/kg phosphate). Do tiny amounts of phosphine in Venus’s clouds prove that life made it? PH4I + NaOH → PH3 + NaI + H2O According to the National Institute for Occupations Safety and Health (NIOSH), a toxic level that can place a person’s life and well-being in jeopardy can be as low as 2 parts per million (ppm). In this case, that means processes beyond those the team simulated. Irritant to eyes and respiratory system, can damage kidneys and other organs. Following their observations, they ran calculations to see whether these amounts could come from natural non-biological processes on the planet. Background. With cooling and pressure, phosgene gas can be converted into a liquid so that it can be shipped and stored. Occupational exposure may occur when workers apply pellets, strips, etc. Last month’s report that there may be phosphine gas in the Venusian clouds came with a stunning implication: extraterrestrial life. Phosphine, H3P, is a very simple molecule. The only ways that phosphine comes into existence on Earth are naturally, produced by bacteria in anaerobic environments, or artificially, produced by humans via controlled chemical reactions. At room temperature (70°F), phosgene is a poisonous gas. On Earth, phosphine, a colourless gas that has the smell of garlic or decaying fish, is produced predominantly by anaerobic biological sources. While it was found that all of those processes are possible on Venus, they cannot account for the concentration of phosphine observed — which comes in at nearly 20 parts per billion. It does give off a smell, similar to garlic. It appears that gas is what caused the deaths and injuries to the family. Although phosphine is highly toxic, it is nonetheless used widely (and usually safely) because of one property—its boiling point. Phosphine gas is also obtained by the action of dilute sulfuric acid from aluminium phosphide. [Phosphine] is found elsewhere in the Solar System only in the reducing atmospheres of gas giant planets, where it is produced in deep atmospheric layers at high temperatures and pressures, and dredged upwards by convection. Phosphine, she points out, is a simple molecule, one that could come from planetary processes we’re not yet privy to. On Earth, phosphine is a gas that is produced predominantly by anaerobic biological sources. Published: 20 October 2020 (GMT+10) Venus. Why is phosphate vital for life? (Phosphine is formed by reaction of the rust inhibitor with welding radiation.) This is the big unanswered question raised by this study. by Jonathan Sarfati. In the outer solar system, phosphine is made deep in the interiors of Jupiter and Saturn. Venus life: Phosphine discovery could be wide of the mark - study THE DISCOVERY that Venus may have life in its atmosphere could be way wide of the mark, according to a new study. Phosphine apparently leaves only parts-per-billion residues in grain after aeration. [1] Exposure to moderate-to-high concentrations of phosgene (>3-4 ppm) can produce an immediate irritant reaction that typically lasts 3-30 minutes and includes the following: 1. Phosphine is heavier than air and may cause asphyxiation … A molecule of phosphine gas consists of a phosphorus atom surrounded by three hydrogen atoms, just like ammonia consists of a nitrogen … See more. Phosphine gas found in Venus’ atmosphere may be ‘a possible sign of life’ Astronomers detected signs of a smelly, toxic gas that microbes can make … or enter closed areas or open containers after the treatment. They release phosphine over a 36-hr period at 25°C. Phosphine gas is colorless, flammable, and toxic. Phosphine (IUPAC name: phosphane) is the compound with the chemical formula PH 3.It is a colorless, flammable, toxic gas. It may only be generated by life-forms on Earth, but that does not rule-out some non-biological process creating it on Venus. 2AlP + 3H2SO4 → Al2(SO4)3 + 2PH3 Phosphine gas is formed by the action of phosphonium iodide with sodium hydroxide. Phosphine gas is generated when calcium phosphide, aluminum phosphide or magnesium phosphide comes in contact with moisture. The addition of red phosphorous will create phosphine gas. Phosphine (or phosphane) is the compound with the chemical formula PH3. The conditions at the surface of Venus are hostile to life, but the environment of its upper cloud deck — around 53–62 km above the surface — is temperate. Where does this phosphine come from? Phosphine gas is a molecule made up of one phosphorus atom and three hydrogen atoms. Lacrimation 2. Sodium hydroxide, added when converting to a base, can rapidly absorb water out of the air and is corrosive to human tissue. The OSHA PEL of 0.3 ppm is within the range of reported odor thresholds. This putrid “swamp gas” is also highly flammable and reactive with particles in … “On Earth, one of the known processes is the production of phosphine gas by aqueous or acid corrosion from phosphorous-containing impurities in iron,” they explain. Near the giant planets’ cores, the temperatures and pressures are extreme enough to … Source: Tables 1 to 3 are from Work Safe Alberta's Welder's Guide to Hazards of Welding Gases and Fumes, 2009 Phosphine is among the stinkiest, most toxic gases on Earth, found in some of the foulest of places, including penguin dung heaps, the depths of swamps and bogs, and even in the bowels of some badgers and fish. Odor is not an adequate indicator of phosphine's presence and may not provide reliable warning of hazardous concentrations. When liquid phosgene is released, it quickly turns into a gas that stays close to the ground and spreads rapidly. There is no a priori reason to expect there are microbes living in Venus' clouds. Phosphine is commonly used as a fumigant in agriculture. Does phosphine prove life on Venus? The researchers ruled out what they believed to be all known chemical means to explain the formation of this molecule. On Earth, phosphine is generated by microbes in oxygen-free environments that are rather unpleasant by human standards — inside the guts of penguins, for example. In mid-September, there were lots of headlines about possible life on Venus. A more recent formulation is sold as 2% phosphine plus 98% carbon dioxide gas (ECO 2 Fume) in a high-pressure gas cylinder. Since phosphine can be emitted by anaerobic organisms, they do not exclude a biological origin, however being very careful: “ Venus has no known non-biological way to produce this molecule in the quantities observed. 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